Euphorbiane: A Novel Triterpenoid with an Unprecedented Skeleton from Euphorbia tirucalli

Euphorbiane ( 1 ), a novel triterpenoid exhibiting a unique skeleton, together with seven known compounds were isolated from the 95% EtOH extract of the fresh stems of Euphorbia tirucalli. The structure of 1 and relative stereochemistry were elucidated by extensive NMR and a single‐crystal X‐ray crystallographic analysis.     

TiO2 Thin Film with Varied Porous Structure Applied on the Degradation of Methylene Blue

In this study, porous TiO₂ thin films were prepared by the sol‐gel method employing polyethylene glycol 1000 (PEG 1000) as an organic template. Pore sizes were adjusted by varying the concentration of PEG 1000. The optimal PEG concentration range required to form TiO₂ films with a regular porous structure was investigated and was found to be 0.01–0.015 M. As the PEG 1000 concentration increased, the surface of these films became rougher because of larger pores. Degradation of methylene blue (MB) under UV irradiation was used to determine the photocatalytic activity of the films. In addition, the effect of the pH value of the MB solution on the films was evaluated by controlling its pH value at 5, 7, and 9. The results showed that the photocatalytic activity was correlated to the pore size and pore density of the thin films. TiO2 thin films possessing pore sizes in the diameter range of 35–85 nm exhibited the best conversion of 98% after 8 h of UV irradiation when the pH value was 7.     

Fuel spray visualization and its impingement analysis on in-cylinder surfaces in a direct-injection spark-ignition engine

Abstract  

Experiments are performed to investigate the effects of fuel spray on in-cylinder mixture preparation and its impingement on cylinder walls and piston top inside a direct-injection spark-ignition engine with optical access to the cylinder. Novel image processing algorithms are developed to analyze the fuel impingement quantitatively on in-cylinder surfaces. The technique is useful to optimize the fuel pressure, injection timing and the number of injections to minimize the fuel impingement on in-cylinder surfaces. E85, which represents a blend of 85% ethanol and 15% gasoline (by volume) is used in this study. Two types of fuel injectors are used; (i) low-pressure production-intent injector with fuel pressure of 3 MPa, and (ii) high-pressure production injector with fuel pressures of 5 and 10 MPa. In addition, the effects of split injection are also presented by maintaining the same amount of fuel used in single injection. It is found that the split injection is an effective way to reduce the overall fuel impingement on in-cylinder surfaces while maintaining a reasonably good air–fuel mixture in the cylinder.     

Improvement of <Emphasis Type="Italic">n</Emphasis>-ZnO/<Emphasis Type="Italic">p</Emphasis>-Si photodiodes by embedding of silver nanoparticles

The photo-current of n-ZnO/p-Si heterojunction photodiodes was improved by embedding Ag nanoparticles in the interface (ZnO/nano-P_Ag/p-Si), and the ratio between photo- and dark-current increased by about three orders more than that of a n-ZnO/p-Si specimen. The improvement in the photo-current resulted from the light scattering of embedded Ag nanoparticles. The I–V curve of n-ZnO/p-Si degraded after thermal treatment (A-ZnO/p-Si) because the silicon robbed the oxygen from ZnO to form amorphous silicon dioxide and left an oxygen vacancy. Notably, the properties of ZnO/nano-P_Ag/p-Si were better in the time-dependent photoresponse under 10 V bias. Ag nanoparticles (15–20 nm) scattered the UV light randomly and increased the probability for the absorption of ZnO to enhance the properties of the photodiode.     

Determination of microelement distribution in different components of soil-plant systems

The leaves, stem, and roots of two types of shrubs (tea (Camellia sinensis) and sweet leaf (Sauropus androgynus)) and two types of herbs (vetiver grass (Vetiveria zizanioides L. Nash) and maize (Zea mays L)) and the Thucuc soil where the plants were growing were collected to be studied. The contents of 22 elements in the samples were determined by three methods: X-Ray fluorescence analysis (XRFA), gamma activation analysis (GAA), and the tracking method to study the distribution of these elements in plants and the soil-plant relationship. This study was carried out at the Flerov Laboratory of Nuclear Reactions (FLNR), Joint Institute for Nuclear Research (JINR), Dubna, Russia. The distribution of the elements in the soil-plant system was studied.     

A heterogeneous cooperative parallel search of branch-and-bound method and tabu search algorithm

In this study, we present a heterogeneous cooperative parallel search that integrates branch-and-bound method and tabu search algorithm. These two algorithms perform searches in parallel and cooperate by asynchronously exchanging information about the best solutions found and new initial solutions for tabu search. The rapid production of a good solution from the tabu search process provides the branch-and-bound process with a better feasible solution to accelerate the elimination of subproblems that do not contain an optimal solution. The new initial solution produced from the subproblem with a least-cost lower bound of the branch-and-bound method suggests the best potential area for tabu search to explore. We use a master-slave model to reduce the complexity of communication and enhance the performance of data exchange. A branch-and-bound process is used as the master process to control the exchange of information and the termination of computation. Several tabu search processes are executed simultaneously as the slave processes and cooperate by asynchronously exchanging information on the best solutions found and the new initial solutions by the master process of branch-and-bound. Based on the computation experiments of solving traveling salesman problems (TSP), the proposed heterogeneous parallel search algorithm outperforms a conventional parallel branch-and-bound method and a conventional parallel tabu search. We also present the computational results showing the efficiency of heterogeneous cooperative parallel search when we use more processors to accelerate search time. Thus, the proposed heterogeneous parallel search algorithm achieves linear accelerations.     

Hybrid control for synchronizing a chaotic system

In this paper, a hybrid control based on pulse width modulator (PWM) is proposed to synchronize a class of master–slave chaotic systems with uncertainties. We use the Genetic Algorithm (GA) together with fuzzy logic to tune the switching time of PWM mode controller such that the output response of master–slave chaotic system can be synchronized. Finally, an example, uncertain master–slave Duffing–Holmes chaos system, is proposed to show the proposed method’s effectiveness for chaotic synchronization.     

An inventory model with generalized type demand,deterioration and backorder rates

This study is motivated by the paper of Skouri et al. [Skouri, Konstantaras, Papachristos, Ganas, European Journal of Operational Research 192 (1) (2009) 79–92]. We extend their inventory model from ramp type demand rate and Weibull deterioration rate to arbitrary demand rate and arbitrary deterioration rate in the consideration of partial backorder. We demonstrate that the optimal solution is actually independent of demand. That is, for a finite time horizon, any attempt at tackling targeted inventory models under ramp type or any other types of the demand becomes redundant. Our analytical approach dramatically simplifies the solution procedure.     

Analytical study of an active piezoelectric absorber on vibration attenuation of a plate

The attenuation of the transverse vibration of a plate, subjected to a harmonic force, is studied. This goal can be achieved by using an active dynamic absorber. The active absorber is made of a pair of piezoelectric sheets, attached to both sides of the plate, and closed electric circuits. One piece of the piezoelectric material provides a sensor for detecting the motion of the plate. Another piece serves as an active dynamic absorber. The equations of motion of the composite plate, including the plate and the piezoelectric material, and the circuit equations of the sensor and the absorber are derived. The displacements of the plate and the currents in the circuits are calculated. The active absorber can successfully attenuate the vibration. The numerical results show that the proposed active absorber can offer more reduction than that using a passive absorber while the absorber is designed to suppress the resonance of a particular vibration mode. Moreover, the active absorber can also reduce the displacements corresponding to other uncontrolled modes. The effects of altering various parameters of the active absorber are studied and discussed.